Fluorescent Lamps:
MATERIAL SAFETY DATA SHEET PRODUCT: Fluorescent Lamp F40T12/Advantage Non ALTO Revised 8/02
SECTION 1: MANUFACTURERManufacturer’s Name and Address: Philip ightingCompanyADivision of Philips Electronics
North America Corporation
200 Franklin Square Drive
Somerset, New Jersey 08875
Emergency Telephone No.: (800) 424-9300 CHEMTREC (732) 563-3197 Safety and Compliance
Other Information Calls: (800) PLC-BULBSECTION 2: HAZARDOUS INGREDIENTSOSHA (PEL) ACGIH (TLV) % by Wt.mg/m
Inert Ingredients (glass, wire, aluminum) approx. 97.5
Phosphor powder & 15 mg/m a nuisance dust
Fluorides (16984-48-8) 2.5 mg/m
Calcium phosphate (68784-55-4) 15 mg/m
Antimony oxide (1309-64-4) .5mg/m
Manganese (7439-96-5) 5.0 mg/m
Barium Magnesium Aluminate None Est’d Less than .1
Yttrium Oxide (68585-82-0) 1.0 mg/m3 mg/m3 TWA3 10mg/m3 Less than 2.03 2.5 mg/m3 approx. .013 10 mg/m3 approx. .053 approx. .023 5.0 mg/m3 approx. .013 l.0 mg/m3 approx. .7MSDS — Fluorescent Lamp F40T12/Advantage Non ALTO
SECTION 2: HAZARDOUS INGREDIENTS(cont’d)OSHA (PEL) ACGIH (TLV) % by Wt.g/m
Lanthanum Phosphate (95823-34-0) None Est’d
Mercury (7439-97-6) l.0 mg/m3 mg/m3 TWA3 .025 mg/m3 Less than .01SECTION
3:CHEMICAL/PHYSICAL DATANot applicable. This item is a light bulb. Up to 8 foot long and up to 1.5 inches in diameter.
SECTION 4: FIRE AND EXPLOSION DATAFIRE AND EXPLOSION DATA NOT APPLICABLE — under extreme heat, glass envelopemight melt or crack.SECTION 5: REACTIVITY DATAStability: Lamp is stable.
Polymerization: Not applicable.
Incompatibility: Glass will react with Hydrofluoric Acid.SECTION 6: HEALTH HAZARD DATANot applicable to the intact lamp. Breakage of the lamp may result in some exposure to the
phosphor powder dust and to a very little amount of elemental mercury vapor. No adverse
affects are expected from occasional exposure to broken lamps, but as a matter of good practice,
prolonged or frequent exposure should be avoided through the use of adequate ventilation during
disposal of large quantities of lamps.
EMERGENCY FIRST AID:
SUCH OCCUR THROUGH LAMP BREAKAGE.NORMAL FIRST AID PROCEDURE FOR GLASS CUTS IFMSDS — Fluorescent Lamp F40T12/Advantage Non ALTO
SECTION 7: PRECAUTIONS FOR SAFE HANDLING AND USAGENormal precautions should be taken for the collection of broken glass.
Waste Disposal Method: At the end of rated life, when this lamp is removed from service, it will
be subjected to the current Toxic Characteristic Leaching Procedure (TCLP) prescribed by the
Environmental Protection Agency. This test is used to determining whether an item is a
hazardous waste or a non-hazardous waste under current E. P. A. definition. These lamps would
fail the TCLP test and would be considered hazardous under the Universal Waste Rules.
Generators should evaluate all of the disposal options, which may be available in the particular
state in which the generator’s facility is located. The generator should check with federal, state
and local officials for their guidance. Philips encourages recycling of its products by qualified
recyclers.
SECTION 8: CONTROL MEASURESRespiratory Protection: None. NIOSH-approved respirator might be used if large volumes of Lamps are being broken for disposal.
Ventilation: Avoid inhalation of any airborne dust. Provide local exhaust when disposing of
large quantities of lamps.
Hand and Eye Protection: Appropriate hand and eye protection should be worn when disposing
of large quantities of lamps or handling broken lamps.SECTION 9: REGULATORY INFORMATIONAs a product these mercury containing lamps being shipped in the manufacturer’s original
packaging are not regulated by air, truck or ocean shipment. As a waste, these spent fluorescent
lamps would be regulated in various states and local communities. This material safety data sheet
does not constitute “knowledge of the waste”, in certain jurisdictions.
S06-96001 May 1996
Revised: 8/02
Batteries:
Lead Acid Batteries:
Form #: MSDS 853020
Revised: 07/05/09
Supersedes: 01/02/08
ECO #: 1000751I. PRODUCT IDENTIFICATION
Chemical Trade Name (as used on label): Chemical Family/Classification:Lead-Acid Battery Electric Storage BatteryManufacturer’s Name/Address: Telephone:EnerSys For information and emergencies, contact EnerSys’
P.O. Box 14145 Environmental, Health & Safety Dept. at 610-208-1996
2366 Bernville Road 24-Hour Emergency Response Contact:Reading, PA 19612-4145 CHEMTREC DOMESTIC: 800-424-9300 CHEMTREC INT’L: 703-527-3877II. HAZARDOUS INGREDIENTS/IDENTIFY INFORMATION
CAS Number Approximate % by Wt. Or Vol.
OSHA ACGIH NIOSH
Inorganic Lead Compound:Lead 7439-92-1 60 50 150 100
* Antimony 7440-36-0 2 500 500 –
* Arsenic 7440-38-2 0.2 10 200 –
* Calcium 7440-70-2 0.2 — – –
* Tin 7440-31-5 0.2 2000 2000 –Electrolyte (Sulfuric Acid) 7664-93-9 10-30 1000 1000 1000Case Material:
Polypropylene 9003-07-0
Polystyrene 9003-53-6
Styrene Acrylonitrile 9003-54-7
Acrylonitrile Butadiene Styrene 9003-56-9
Styrene Butadiene 9003-55-8
Polyvinylchloride 9002-86-2
Polycarbonate, Hard Rubber, Polyethylene –5-10:Silicon Dioxide (Gel batteries only) 7631-86-9 20-40
Sheet Molding Compound
(Glass reinforced polyester)
Inorganic lead and electrolyte (sulfuric acid) are the primary components of every battery manufactured by EnerSys.
Other ingredients may be present dependent upon battery type. Contact your EnerSys representative for additonal information.III. PHYSICAL DATA
Electrolyte:
Boiling Point: 203 – 240° F Specific Gravity (H2O = 1): 1.215 to 1.350Melting Point: N/A Vapor Pressure (mm Hg): 10Solubility in Water: 100% Vapor Density (AIR = 1): Greater than 1Evaporation Rate: (Butyl Acetate = 1) Less than 1 % Volatile by Weight: N/AAppearance and Odor: Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.IV. FIRE AND EXPLOSION HAZARD DATA
Flash Point: N/A Flammable Limits: LEL = 4.1% (Hydrogen Gas) UEL = 74.2%Extiguishing Media: CO2; foam; dry chemicalSpecial Fire Fighting Procedures:If batteries are on charge, shut off power. Use positive pressure, self-contained breathing apparatus. Water applied to electrolyte generates
heat and causes it to spatter. Wear acid-resistant clothing.Unusual Fire and Explosion Hazards:Highly flammable hydrogen gas is generated during charging and operation of batteries. To avoid risk of fire or explosion, keep sparks or other sources of ignition away from batteries. Do not allow metallic materials to simultaneously contact negative and positive terminals of cells and batteries. Follow manufacturer’s instructions for installation and service.
V. REACTIVITY DATA
Stability: StableConditions To Avoid: Prolonged overcharge; sources of ignitionIncompatibility: (Materials to avoid)Sulfuric Acid: Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. Lead Compounds: Avoid contact with strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen and reducing agents.Hazardous Decomposition Products:Sulfuric Acid: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, and hydrogen. lead Compounds: High temperatures likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas.MATERIAL SAFETY DATA SHEETAir Exposure Limits (ug/m
Ni-Cad Batteries:
Form # MSDS 853025
Revised: 07/05/09
Supersedes: 07/31/07
ECO #: 1000751I. PRODUCT IDENTIFICATION
Chemical Trade Name (as used on label): Chemical Family/Classification:Industrial Nickel Cadmium Storage Battery w/ Pocket Plate N/A
(VARTA T, TP and TSP range)Manufacturer’s Name/Address: Telephone:EnerSys For information and emergencies, contact EnerSys’
P.O. Box 14145 Environmental, Health & Safety Dept. at 610-208-1996
2366 Bernville Road 24-Hour Emergency Response Contact:Reading, PA 19612-4145 CHEMTREC DOMESTIC: 800-424-9300 CHEMTREC INT’L: 703-527-3877II. HAZARDOUS INGREDIENTS/IDENTIFY INFORMATION
CAS Number Approximate % by Wt. Or Vol.
OSHA ACGIH NIOSHNickel (As Nickel and 7440-02-0 9-10 1.0 0.1 0.015
Nickel hydroxide) 1205-44-87
Cadmium (As Cadmium 7440-43-9 8-10 0.005 0.01 N/A
And Cadmium Hydroxide) 21041-95-2
Iron (Fe) 7439-89-6 20-25 10.0 5.0 5.0
Stainless Steel (Fe, Ni, Cr) N/A 7-15 N/A N/A N/A
Cobalt (as Cobalt hydroxide) 7440-48-4 0 0.1 0.02 0.05
Potassium hydroxide Solution 1310-58-3 30-40 N/A N/A 2.0
(KOH)
Lithium Hydroxide Solution (LiOH) 1310-66-3 <1 N/A N/A N/AIII. PHYSICAL DATA
Electrolyte: boiling Point: N/A Specific Gravity (H2O = 1): 1.2 kg/lMelting Point:
Solubility in Water: Evaporation Rate: (Butyl Acetate = 1) % Volatile by Weight:N/A Vapor Pressure (mm Hg):100% Vapor Density (AIR = 1):(Butyl acetate = 1)Appearance and Odor: Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.IV. FIRE AND EXPLOSION HAZARD DATA
Flash Point: N/A Flammable Limits: LEL = N/A UEL =N/AExtinguishing Media: Dry chemical, CO2, water spray, or alcohol-resistant foam.Special Fire Fighting Procedures:Use full body protective clothing and full face piece. Self-contained breather apparatus in a positive pressure mode. Molted and overheated Cd and Ni produce fume, vapor or dust. Under these conditions, Ni or Cd is suspected carcinogen. KOH is highly caustic. Contact with eye and skin must be avoided. No heating or smoking during handling or inspection. Do not cause sparks.
V. REACTIVITY DATA
Stability: StableConditions To Avoid: Avoid shorting batteries such as contacting across terminals with any metal object. Avoid continuous temperatures over 190 degrees F.Incompatibility: (Materials to avoid)Do not fill cells with Lead Acid Battery electrolyte (Sulfuric Acid).Hazardous Decomposition Products:Nickel compounds, Cadmium compounds, and caustic liquid.VI. HEALTH HAZARD DATA
Inhalation:Fumes irritate nose and throat but fumes generated only if batteries are on charge (not a transportation condition).Ingestion:Severe irritation of internal tissues. Contact physician immediately.Skin Contact:Sever irritation and inflammation. Flush with water. Obtain medical attention.Skin Absorption:Severe irritation and inflammation. Flush with water. Obtain medical attention.Eye Contact:Severe irritation. Possible corneal damage. Flush with water for 15 minutes.MATERIAL SAFETY DATA SHEETAir Exposure Limits (ug/m
Lithuim Batteries:
1-4Manufacturer Phone Number (For Information)
Street Address Emergency Phone NumberCHEMTREC INT’L: 703-527-3877City, State, ZipSECTION 1- PRODUCT IDENTIFICATIONProduct name:Model:
Nominal Voltage: 12,24,36,48VDesignated for recharge: YesSECTION 2-MATERIAL IDENTIFICATION AND INFORMATIONOSHA ACGIH OTHER LIMITS
PEL TLV RECOMMENDED28.0 16.0 15 mppcfa 21.5 6.5 48.0
Subtotal of contents of Lithium Ion Battery 100
78-80
20-22
Total battery + non-battery components 100SECTION 3- PHYSICAL /CHEMICAL CHARACTERISTICSSpecific Gravity (H2O=1)
Melting PointLiCoO2: 1130°CAppearance and OdorSECTION 4- FIRE AND EXPLOSION HAZARD DATAExtinguisher MediaWater, CO2 or dry chemical powderSpecial Fire-Fighting ProceduresSmoke may contain irritants to skin, eyes and respiratory track. The battery packs are constructed of many small cells.
Cells can expel hot gas and smoke if they are exposed to temperatures of greater than 130°C for more than 10 minutes.
C02 or chemical powder may extinguish flamable materials prevent restart of fire. no new release of smoke for 1 hour before assuming the battery is extinguished. Residue left after burning is primarily
carbon but may contain small amounts of Hydrofluoric Acid. Use protective gloves and eye protection. Avoid inhalation of from residue.surrounding battery, but battery container must be cooled toWater is a suitable material for extinguishing flames and cooling battery. Wait until there isA manufactured article containing lithium ion cells. powder; Organic solvent is a colorless liquid;Lithium salt is a white, crystlalline and odorless powder.
LiCoO2:3.80 LiCoO2 is a gray odorless powder;Graphite is a black or odorlessGraphite:2.0 – 2.2Modular Energy Devices
20 Altieri Way,Unit 4,
Warwick, RI 02886
401-921-5370Chemtrec Domestic 1-800-424-93Battery Pack, includes
ion Batteries
RKU,ARM,PNU,MPS SeriesHigh Energy Lithium4. Organic solvent
1. Lithium CobaltiteMaterial Safety Data Sheet MSDS 853028 1/4COMPONENTS-Chemical Name and Common Names% by wt.Lithium Ion Cell – Contents:
2. Graphite Carbon
3. Lithium Hexafluorophosphate(Hazardous Components 1% or greater, Carcinogens 0.1% or greater)Percent by wt of Battery
Percent wt of non-battery components
5. Non-Hazardous Ingredients